The effort is being backed by the British Phonographic Industry (BPI), which represents the recorded music industry in the UK.
They want the children to understand that it is not just artists who lose out to piracy. "A whole army of people work behind the scenes to bring you new, fresh music," said Paul Shedden, Head of Label at Shed Records.
"Everything from the songwriters through to production, artists, engineers, radio pluggers, PR companies all those people need to get paid. Otherwise they can't continue doing the jobs they love and the music you love will stop coming out."
Currently, the scheme is targeting five schools as a trial, and if successful, the plan is to extend nationally, with other labels around the country providing similar sessions in schools.